DEOCRYSTAL STONE ALUM
Date: February
2016
1. Product and Supplier Description
Trade Name: Alum Stone
INCI Name: Potassium Alum
Supplier:
ORIENTAL GROUP SARL AU
N°200 Lot El Massar, Route de Safi
40 100 Marrakech
MOROCCO
Tel :+212 524 335 449
Fax : +212 524 457 961
Mobile / Whatsapp / Viber : +212 600 604 387
Skype :
group.oriental
E-mail : contact@group-oriental.com
1.1 Relevant identified uses of the substance and uses advised against Use
of product: bacteriostatic agents for cosmetic products
like deodorants.
2. Hazards Identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Eye Irrit. 2 H319 Causes serious eye irritation.
Classification according to Directive No 67 /548/EEC / Directive
1999/45/EC
Xn: Harmful
R36: Irritating to eyes
Further information on health effects and symptoms can be found in
Section 11.
2.2 Labelling elements
LABEL IN ACCORDANCE WITH (EC) NO. 1272/2008
HAZARD PICTOGRAM(S)
GHS07
SIGNAL WORD: Danger.
HAZARD
STATEMENT(S)
H319 Causes serious eye irritation.
PRECAUTIONARY
STATEMENT(S)
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for
several minutes. Remove contact lenses, if present and easy to do. Continue to
rinse.
P337 + P313 If eye irritation persists: Get medical advice/attention.
P235 Keep cool.
Labelling according to Council Directive 67/548 / EC / Directive 1999/45
/ EC Index number: 607-163-00-2
Symbols:
Irritant
Risk Phrases:
R36 Irritating to eyes.
Safety Phrases:
S 26 In case of
contact with eyes, rinse immediately with plenty of water and consult a
physician.
2.3. Other hazards
Other hazards which do not result in classification: not available.
3. Composition and Ingredient Information
3.1
Chemical identity of the substance
Substance /
preparation:
·
Without preservatives or other additives.
INCI name: Potassium Alum.
Chemical Name: Aluminum potassium bis
(sulfate)
Potassium aluminum sulfate 12-hydrate
Chemical Formula: KAl(SO4)2 ∙ 12O H
CAS No.: 10043-67-1 / 7784-24-9
EC No.: 233-141-3
Classification: Xi; R36 Eye Irrit. 2;
H319
Content: 100 %
See Section 16
for the above-listed risk phrases and hazard statements reads in full text.
4. First Aid Measures
4.1 Description of first aid measure
Inhalation:
·
Remove to fresh air and
rest.
· If irritation develops seek medical assistance
Skin Contact: Not expected to require first aid
measures.
Eyes Contact: Hold eyes open, rinse
with copious amounts of water and if irritation persists seek medical
assistance.
Ingestion:
·
Rinse mouth with water,
drink plenty of water and seek medical advice.
·
DO NOT induce vomiting.
·
If a large amount is
swallowed, contact a doctor.
5.
Fire Fighting Measures
5.1 Extinguishing media
Suitable extinguishing media: Carbon dioxide (CO2) dry powder, or foam.
Unsuitable extinguishing media: Do not use water jet directly on burning material.
5.2
Special hazards arising from the substance
·
Non-combustible.
·
When heated to high temperatures or fire may
be poisonous gas formed.
5.3
Advice to fire-fighters
·
Containers close to the
fire should be removed or cooled with water.
·
Avoid inhalation.
·
Avoid breathing in vapour or smoke emitted.
·
Use breathing apparatus to protect from fumes.
6.
Measures in case of accidental release
6.1 Personal safety precautions, protective equipment and emergency
procedures
·
Avoid dust formation.
·
Use personal protective equipment.
6.2
Environmental precautions
·
Do not empty into drains.
6.3 Containment and cleaning methods and equipment
Methods of
Cleaning/Disposal:
·
Sweep up or vacuum up
spillage and collect in suitable waste container.
·
Do not flush into surface water or sanitary
sewer system.
6.4
Reference to other sections
·
For safe handling, see
section 7
·
For personal protection,
see section 8.
·
For disposal information, see section 13.
7. Handling and Storage
7.1 Precautions for safe handling
Safe Handling:
·
Avoid formation of dust.
·
Avoid contact with skin,
eyes and clothing.
·
Handle in accordance with
good industrial hygiene and safety.
7.1 Conditions for
safe storage, including any incompatibilities
·
Store in full, tightly
sealed original containers in a cool, dry, well-ventilated place.
·
Protect from light and
heat.
Observe Good
Manufacturing Practices.
8. Exposure Controls/Personal Protection
8.1 Control Parameters
Components with limit values
AFS 2011: 18 Aluminum, soluble compounds (Al) - Total dust: TWA (TWA, 1996): 1 mg / m3
8.2
Exposure Controls:
Personal protective
equipment:
Respirator if there is dust formation: use respirator with an approved filter type P1 (EN143). Hand Protection: Wear suitable
gloves type N65.
Eye protection:
·
Not necessary.
·
If dust or splashing, wear safety glasses with
side protection.
Skin and body protection:
·
No special protective equipment required.
·
Upon repeated contact, wear protective
clothing.
Hygiene measures:
·
Wash hands before breaks and immediately after
handling the subject.
·
Do not eat, drink, sniff or smoke while
handling the product.
·
Ability to eyewash and safety shower should be
available at workplace.
Environmental exposure:
General advice: Avoid the subject comes
into the sewer system.
9. Physical and Chemical Properties
9.1 Information on physical and chemical properties
Appearance:
·
Physical State: Crystals.
·
Colour: White.
Odour: Odourless.
pH: 3 to 3.5 (10% in
water).
Melting Point: 92.5 ° C
Flash Point: Not applicable.
Density: 1.5 g / cm3
Bulk density: No information available.
Solubility:
·
Soluble in water: 110g /
l (20 ° C).
·
Insoluble in ethanol.
9.2
Other information
·
No information available.
10. Stability and Reactivity
10.1 Reactivity
·
No known reactivity
hazards associated with this topic.
10.2
Chemical stability
·
Stable with normal
handling and storage conditions.
10.3 Possibility of hazardous reactions
·
No information available.
10.4 Conditions to avoid
·
No information available.
10.5
Incompatible materials
·
Alkali hydroxides and
carbonates. Salts of calcium, lead and phosphates mm.
10.6 Hazardous decomposition products
·
When heated to
decomposition (> 200 ° C) or at a fire, toxic gas formed, sulfur trioxide.
11.
Toxicological Information
11.1 Information on toxicological effects
11.1.1 Acute
toxicity
· Not classified as acutely toxic according to EU Regulations 1272/2008
and 286/2011 (second ATP).
· Ingestion
(aluminum potassium sulfate): Oral TDLo rats: 4355 - 8040mg / kg.
· Ingestion (aluminum potassium sulfate, dodecahydrate): Oral TDLo rat: 1120mg / kg.
· Reference
"SAX's Dangerous Properties of Industrial Materials".
11.1.2 Corrosion / irritation
The airways: The airways Inhalation of
dust may irritate the nose and throat and cause coughing.
Skin: May cause irritation, especially after repeated
exposure. Eye: Dust can irritate the eyes.
Ingestion: Gastrointestinal Ingestion of powder and concentrated solution may cause
pain in the mouth and throat and stomach pains.
11.1.3 Sensitization
· Skin: Not classified as a sensitizer according to EU
regulations 1272/2008 and 286/2011 (2 ATP).
· Source ECHA.
11.1.4 CMR effects (carcinogenicity, mutagenicity and toxicity for
reproduction)
· No carcinogenic,
mutagenic effect in rats.
· Reproductive
toxicity in rats - no information available.
· Source ECHA.
11.1.5 Aspiration
· No information
available.
12. Ecological Information
12.1 Toxicity
Not classified as dangerous for the
environment.
·
Aluminum ion is itself
highly toxic to aquatic organisms, but the bioavailability at normal pH values
is low as insoluble hydroxides are formed.
12.2 Persistence and degradability
·
Not applicable.
·
Inorganic compound.
13.
Disposal Considerations
13.1 Waste treatment
·
Hazardous waste.
·
Consult local authorities
for waste disposal.
13.2 Uncleaned packaging
·
Not empty containers
should be taken as a hazardous waste to an approved waste facility
14.
Transport Information
·
Not dangerous according to ADR, IATA, IMDG and
RID.
·
No restrictions.
15.
Regulatory Information
15.1 Safety, health and environmental regulations/legislation specific
for the substance or mixture
Labelling according to Regulation (EC) No 1272/2008 Hazard symbols
GHS07
SIGNAL WORD: Danger.
HAZARD STATEMENT(S)
H319 Causes serious eye irritation.
PRECAUTIONARY STATEMENT(S)
P280 Wear protective gloves/protective clothing/eye protection/face
protection.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for
several minutes. Remove contact lenses, if present and easy to do. Continue to
rinse.
P337 + P313 If eye irritation persists: Get medical advice/attention.
P235 Keep cool.
P501: Dispose of
contents/container…accordance towith… [ local/regional/national/international
regulation
Other:
·
Water hazard class (Germany): Water hazard
class 1 small hazard to water
15.2
Chemical Safety
·
No information available.
16. Other Information
The information contained herein is accurate to the best of our knowledge at the time and on the date shown from a variety of sources. No liability can be accepted arising out of the use, application or processing of this producte. It conditions for use of this product.
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