Green Apple

Creation date: 01/02/2018       

IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING

1.   

1.1   Trade Name: Green Apple

1.2   Use : industrial, reserved for professional use.

 

1.3 Company identification: ORIENTAL GROUP SARL AU.

N°200 Lot ALMASSAR, Route de safi, 40 100 Marrakesh, MOROCCO

Tel.: +212 524 335 449

E-mail: contact@group-oriental.com 

Site web    : www.group-oriental.com

1.3   Emergency tel : +212 600 604 387

HAZARD IDENTIFICATION

1- Classification of the substance or mixture

Classification GHS :

CLP legislation

EHC2 Hazards to the aquatic environment – ​​chronic 2

SS1 Skin sensitization 1

H317 May cause an allergic skin reaction.

H412 Harmful to aquatic life with long lasting effects.

EUH208 Contains (name of the sensitizing substance). May produce an allergic reaction. Classification according to EU Directives 67/548/EEC and 1999/45/EC

Health risks: Xn

R43: May cause sensitization by skin contact.

R48 Risk of serious damage to health by prolonged exposure

Environmental risks: N

R51/53 toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment

2- Labeling elements

Classification GHS :

CLP legislation

Warning notice: CAUTION

EHC2 Hazards to the aquatic environment – ​​chronic 2

SS1 Skin sensitization - category 1

H317 May cause an allergic skin reaction.

H412 Harmful to aquatic life with long lasting effects.

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P272 Contaminated work clothing should not be allowed out of the workplace.

P273 Avoid release to the environment

P280 Wear protective gloves/protective clothing/eye protection/face protection P302+P352 IF ON SKIN: Wash with plenty of soap and water

P333+P313 If skin irritation or rash occurs: Get medical advice/attention.

EUH208 Contains (name of the sensitizing substance). May produce an allergic reaction.

 
 

Classification according to EU Directives 67/548/EEC and 1999/45/EC
 

Health risks: Xn

R43: May cause sensitization by skin contact.

R48 Risk of serious damage to health by prolonged exposure

Environmental risks:

R51/53 toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment

S60: Dispose of the product and its container as hazardous waste.

S24 Avoid contact with ski

3-Other dangers

Contient : 2-tert-Butylcyclohexyl acetate ; allyl heptanoate ; hexyl salicylate ; hexyl cinnamal

COMPOSITION/INFORMATION ON COMPONENTS

•         Composition: Mixture of synthetic and/or natural aromatic raw materials

FIRST AID

•         Description of first aid: not applicable

•         Main symptoms and effects, acute and delayed: not applicable

•         Indication of any immediate medical attention and special treatment required:

- Contact with eyes: rinse thoroughly with water (15 minutes with the eyelids open) then wash with an eye lotion such as dacryoserum. If trouble occurs, consult an ophthalmologist.

- Contact with skin: wash immediately and abundantly with soap and water. Then rinse with clean water

- In case of ingestion: if the symptoms persist, consult a doctor.

- Soiled clothing: remove soiled clothing and only reuse it after decontamination.

FIRE FIGHTING MEASURES

•         Extinguishing media: CO2, extinguishing powder or water spray. Fight large fires with water spray or alcohol-resistant foam.

• Special hazards arising from the substance or mixture:

- Flammability class: the product is not flammable

-         Prevention: no smoking, no open flames

•         Advice to firefighters: never use a direct jet of water

MEASURES TO BE TAKEN IN THE EVENT OF ACCIDENTAL RELEASE

•         Personal precautions : Provide adequate protection for cleaning crews. Respiratory protective equipment may be required.

•         Environmental precautions : prevent any contamination of soil and water, any flow into sewers, gutters, rivers, notify the authorities if the product enters the sewers or public waters

•         Cleaning methods : damming with sand or diatomaceous earth, pumping and rinsing with water after recovery of waste in plastic and labeled drums to then be handed over to an approved collector.

HANDLING AND STORAGE

•         Precautions to take for safe handling : Close the packaging after use.

Reproduce the labeling if transferring to another container

•         Conditions necessary to ensure storage safety :

Avoid unnecessary explosion. Keep away from food and drink.

Store only in original container in a cool, well-ventilated place.

Keep closed containers out of use

Away from heat sources, direct sunlight

•         Specific end use : Wash hands and other exposed areas with mild soap and water before eating, drinking, using tobacco and when leaving work.

8- EXPOSURE CONTROL/PERSONAL PROTECTION

•         Technical measures : avoid contact with eyes, skin or clothing. Do not ingest. Avoid contact with food and drink.

•         Respiratory protection : in case of insufficient ventilation, wear suitable respiratory equipment.

•         Skin protection : handle the product with gloves appropriate to the risk.

•         Eye protection : protection not required if sufficient ventilation is maintained.

•         Ingestion : Do not eat, drink or smoke during use.

9- PHYSICAL AND CHEMICAL PROPERTIES

•         Appearance: Liquid

•         Color: Colorless to pale yellow

•         Smell: Apple

•         Relative density (d20/20):   [0.9632, 1.0632]

•         Rotational power in °

• Refractive index [1.4501, 1.4701]

• Flash point 90°C

•         Chromatographic analysis Ok

•         Solubility in water        No

•         Solubility in ethanol    Yes

STABILITY AND RESPONSIVENESS

•         Chemical stability : not concerned

•         Reactivity : not concerned

•         Possibility of dangerous reactions : not applicable

•         Conditions to avoid : not applicable

•         Incompatible materials : not applicable

•         Dangerous decomposition products :

-         Thermal decomposition/conditions to avoid : no decomposition if used as directed.

-         Hazardous decomposition products : no decomposition products in normal use

TOXICOLOGICAL INFORMATION

•         Toxicological information : No data available

•         Acute toxicity information :

-         Oral : not determined

-         Inhalation : not determined

-         Cutaneous : not determined

ECOLOGICAL INFORMATION

•         Toxicity : Do not let the product, undiluted or in large quantities penetrate the water table, water or pipes.

•         Persistence and degradability : not concerned

•         Bioaccumulation potential : not concerned

•         Mobility in soil : not concerned

• Results of PBT and vPvB assessments: not applicable

•         Other adverse effects : not concerned

DISPOSAL CONSIDERATIONS

•         Waste treatment methods

- Product: recommendation: must not be disposed of with household waste.

         Do not allow to enter drains.

- Uncleaned packaging: recommendation: disposal in accordance with legal requirements

INFORMATIONS RELATIVES AU TRANSPORT

• UN number

ADR: not applicable

IMDG: not applicable

IATA: not concerned

• UN proper shipping name

ADR: not applicable

IMDG: not applicable

IATA: not concerned

• ADR transport hazard class: not applicable

IMDG: not concerned

IATA: not concerned

• Packing group

ADR: not applicable

IMDG: not applicable

IATA: not concerned

• Environmental hazards

IMDG: not applicable

• Special precautions to be taken by the user: not applicable

• Transport in bulk in accordance with Annex II of MARPOL 73/78 and the IBC Code

It does not concern

REGULATORY INFORMATION

It does not concern

OTHER DATA

Safety data sheet according to 2001/58/EEC

The data described correspond to the current information in force and do not represent a guarantee of the properties.

The recipient of our product must follow the legal requirements of the country that refers to this product.

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DEOCRYSTAL STONE ALUM

 

Date: February 2016

 

1. Product and Supplier Description

 

Trade Name: Alum Stone

 

INCI Name: Potassium Alum

 

Supplier:

 

ORIENTAL GROUP SARL AU

N°200 Lot El Massar, Route de Safi

40 100 Marrakech

MOROCCO

Tel :+212 524 335 449

Fax : +212 524 457 961

Mobile / Whatsapp / Viber : +212 600 604 387

Skype : group.oriental

E-mail : contact@group-oriental.com

 

1.1  Relevant identified uses of the substance and uses advised against Use of product: bacteriostatic agents for cosmetic products like deodorants.

 

 

 

2.  Hazards Identification

 

 

2.1  Classification of the substance or mixture

 

Classification according to Regulation (EC) No 1272/2008

 

Eye Irrit. 2 H319 Causes serious eye irritation.

 

Classification according to Directive No 67 /548/EEC / Directive 1999/45/EC

Xn: Harmful

 

R36: Irritating to eyes

 

Further information on health effects and symptoms can be found in Section 11.

 

2.2 Labelling elements

 

LABEL IN ACCORDANCE WITH (EC) NO. 1272/2008

 

 

HAZARD PICTOGRAM(S)

GHS07

 

SIGNAL WORD: Danger.

HAZARD STATEMENT(S)

H319 Causes serious eye irritation.

 

PRECAUTIONARY STATEMENT(S)

P280 Wear protective gloves/protective clothing/eye protection/face protection.

 

P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue to rinse.

 

P337 + P313 If eye irritation persists: Get medical advice/attention. P235 Keep cool.

 

 

 

Labelling according to Council Directive 67/548 / EC / Directive 1999/45 / EC Index number: 607-163-00-2

 

Symbols:

 

 Irritant

 

Risk Phrases:

 

R36 Irritating to eyes.

 

Safety Phrases:

 

S 26 In case of contact with eyes, rinse immediately with plenty of water and consult a physician.

 

2.3. Other hazards

 

Other hazards which do not result in classification: not available.

 

 

3.  Composition and Ingredient Information

 

3.1  Chemical identity of the substance

 

Substance / preparation:

 

·        Without preservatives or other additives.

 

INCI name: Potassium Alum.

 

Chemical Name: Aluminum potassium bis (sulfate)

 

Potassium aluminum sulfate 12-hydrate

 

Chemical Formula: KAl(SO4)2 ∙  12O  H

 

CAS No.: 10043-67-1 / 7784-24-9

 

EC No.: 233-141-3

 

Classification: Xi; R36 Eye Irrit. 2; H319

 

Content: 100 %

 

See Section 16 for the above-listed risk phrases and hazard statements reads in full text.

 

 

4.  First Aid Measures

 

4.1 Description of first aid measure

 

Inhalation:

 

·         Remove to fresh air and rest.

 

·         If irritation develops seek medical assistance 

Skin Contact: Not expected to require first aid measures.

 

Eyes Contact: Hold eyes open, rinse with copious amounts of water and if irritation persists seek medical assistance.

 

Ingestion:

 

·         Rinse mouth with water, drink plenty of water and seek medical advice.

 

·         DO NOT induce vomiting.

 

·         If a large amount is swallowed, contact a doctor.

 

 

5.  Fire Fighting Measures

 

 

5.1  Extinguishing media

 

Suitable extinguishing media: Carbon dioxide (CO2) dry powder, or foam.

Unsuitable extinguishing media: Do not use water jet directly on burning material.

 

5.2 Special hazards arising from the substance

·         Non-combustible.

 

·         When heated to high temperatures or fire may be poisonous gas formed.

5.3  Advice to fire-fighters

 

·         Containers close to the fire should be removed or cooled with water.

 

·         Avoid inhalation.

 

·         Avoid breathing in vapour or smoke emitted.

 

·         Use breathing apparatus to protect from fumes.

 

6.  Measures in case of accidental release

 

6.1 Personal safety precautions, protective equipment and emergency procedures

 

·         Avoid dust formation.

 

·         Use personal protective equipment.

6.2  Environmental precautions

 

·         Do not empty into drains.

6.3  Containment and cleaning methods and equipment

 

Methods of Cleaning/Disposal:

·         Sweep up or vacuum up spillage and collect in suitable waste container.

 

·         Do not flush into surface water or sanitary sewer system.

 

6.4 Reference to other sections

 

·         For safe handling, see section 7

·         For personal protection, see section 8.

 

·         For disposal information, see section 13.

 

 

7.  Handling and Storage

 

7.1 Precautions for safe handling

Safe Handling:

·        Avoid formation of dust.

 

·        Avoid contact with skin, eyes and clothing.

·         Handle in accordance with good industrial hygiene and safety.

 

7.1  Conditions for safe storage, including any incompatibilities

·         Store in full, tightly sealed original containers in a cool, dry, well-ventilated place.

 

·         Protect from light and heat.

 

Observe Good Manufacturing Practices.

 

 

8. Exposure Controls/Personal Protection

 

8.1  Control Parameters

Components with limit values

 

AFS 2011: 18 Aluminum, soluble compounds (Al) - Total dust: TWA (TWA, 1996): 1 mg / m³

8.2  Exposure Controls:

Personal protective equipment:

 

Respirator if there is dust formation: use respirator with an approved filter type P1 (EN143). Hand Protection: Wear suitable gloves type N65.

 

Eye protection:

 

·         Not necessary.

 

·         If dust or splashing, wear safety glasses with side protection.

 

Skin and body protection:

 

·         No special protective equipment required.

 

·         Upon repeated contact, wear protective clothing.

 

Hygiene measures:

 

·         Wash hands before breaks and immediately after handling the subject.

 

·         Do not eat, drink, sniff or smoke while handling the product.

 

·         Ability to eyewash and safety shower should be available at workplace.

 

Environmental exposure:

 

General advice: Avoid the subject comes into the sewer system.

 

 

9.  Physical and Chemical Properties

 

9.1  Information on physical and chemical properties

 

Appearance:

 

·         Physical State: Crystals.

 

·         Colour: White.

 

Odour: Odourless.

 

pH: 3 to 3.5 (10% in water).

 

Melting Point: 92.5 ° C

 

Flash Point: Not applicable.

 

Density: 1.5 g / cm³

Bulk density: No information available.

 

Solubility:

 

·         Soluble in water: 110g / l (20 ° C).

 

·         Insoluble in ethanol.

 

9.2  Other information

 

·         No information available.

 

 

10. Stability and Reactivity

 

10.1  Reactivity

 

·         No known reactivity hazards associated with this topic.

 

10.2  Chemical stability

 

·         Stable with normal handling and storage conditions.

 

10.3  Possibility of hazardous reactions

·         No information available.

 

10.4  Conditions to avoid

·         No information available.

10.5  Incompatible materials

 

·         Alkali hydroxides and carbonates. Salts of calcium, lead and phosphates mm.

 

10.6  Hazardous decomposition products

 

·        When heated to decomposition (> 200 ° C) or at a fire, toxic gas formed, sulfur trioxide.

 

 

11.   Toxicological Information

 

11.1  Information on toxicological effects

11.1.1 Acute toxicity

 

· Not classified as acutely toxic according to EU Regulations 1272/2008 and 286/2011 (second ATP).

 

· Ingestion (aluminum potassium sulfate): Oral TDLo rats: 4355 - 8040mg / kg.

· Ingestion (aluminum potassium sulfate, dodecahydrate): Oral TDLo rat: 1120mg / kg.

 

· Reference "SAX's Dangerous Properties of Industrial Materials".

 

11.1.2 Corrosion / irritation

 

The airways: The airways Inhalation of dust may irritate the nose and throat and cause coughing.

 

Skin: May cause irritation, especially after repeated exposure. Eye: Dust can irritate the eyes.

 

Ingestion: Gastrointestinal Ingestion of powder and concentrated solution may cause pain in the mouth and throat and stomach pains.

11.1.3 Sensitization

 

· Skin: Not classified as a sensitizer according to EU regulations 1272/2008 and 286/2011 (2 ATP).

 

· Source ECHA.

 

11.1.4 CMR effects (carcinogenicity, mutagenicity and toxicity for reproduction)

 

· No carcinogenic, mutagenic effect in rats.

 

· Reproductive toxicity in rats - no information available.

 

· Source ECHA.

 

11.1.5 Aspiration

 

· No information available.

 

12. Ecological Information

 

12.1 Toxicity

Not classified as dangerous for the environment.

 

·         Aluminum ion is itself highly toxic to aquatic organisms, but the bioavailability at normal pH values is low as insoluble hydroxides are formed.

 

12.2  Persistence and degradability

 

·         Not applicable.

 

·         Inorganic compound.

 

 

13.   Disposal Considerations

 

13.1  Waste treatment

 

·         Hazardous waste.

 

·         Consult local authorities for waste disposal.

 

13.2 Uncleaned packaging

 

·         Not empty containers should be taken as a hazardous waste to an approved waste facility

 

 

14.   Transport Information

 

·         Not dangerous according to ADR, IATA, IMDG and RID.

 

·         No restrictions.

 

 

15.   Regulatory Information

 

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

 

Labelling according to Regulation (EC) No 1272/2008 Hazard symbols

 

GHS07

 

SIGNAL WORD: Danger.

 

HAZARD STATEMENT(S)

 

H319 Causes serious eye irritation.

 

PRECAUTIONARY STATEMENT(S)

 

P280 Wear protective gloves/protective clothing/eye protection/face protection.

 

P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue to rinse.

 

P337 + P313 If eye irritation persists: Get medical advice/attention. P235 Keep cool.

 

P501: Dispose of contents/container…accordance towith… [ local/regional/national/international regulation

 

Other:

 

·         Water hazard class (Germany): Water hazard class 1 small hazard to water

 

15.2  Chemical Safety

 

·         No information available.

 

 

 

 

 

16. Other Information

The information contained herein is accurate to the best of our knowledge at the time and on the date shown from a variety of sources. No liability can be accepted arising out of the use, application or processing of this producte. It conditions for use of this product.

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https://group-oriental.com/

https://oriental-group-bulk-argan-oil.blogspot.com/

https://argan-oil-factory-morocco.blogspot.com/

https://arganismemoroccanoil.blogspot.com/

https://bioprogreen-morocco.blogspot.com/